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化学系副教授。桂林工学院本科毕业，河南师范大学理学硕士，南开大学理学博士，北京大学化学与分子工程学院博士后。研究领域为多相催化，重点关注催化剂表面结构与催化活性的构效关系，以及探索化学反应的催化机理。目前已在SCI期刊发表论文90多篇，主持和参研国家和省部级项目近10项。主讲课程有《物理化学》（本科）、《晶体化学基础》（本科），《结晶化学导论》（研究生），已参编《物理化学》、《无机化学》等教材4部。 |
联系方式
办公地点：虎溪校区理科楼LC416；实验室LC334
电子邮箱：gaowl@cqu.edu.cn电话：13452079116
研究方向
代表性论文、专著和专利
1) D. Wang, Y. Yang, F. H. Zhang, P. F. Jiang, W. L Gao,* R. H. Cong, T. Yang*, Ring-Opening Hydration of Epoxides into Diols with a Low Water−Epoxide Ratio Catalyzed by a Fe-Incorporated Octahedra-Based Molecular Sieve, J. Phys. Chem. C 2021, 125, 13291−13303
2) W. L. Wang, Y. He, J. K. He, Y. L. Dang, T. Kankanmkapuge, W. L. Gao,* R. H. Cong, S. L. Suib,* T. Yang,* Identification of key oxidative intermediates and the function of chromium dopants in PKU-8: catalytic dehydrogenation of sec-alcohols with tert-butylhydroperoxide，Catal. Sci. Technol., 2021, 11, 1365
3) Y. Yang, D. Wang, P. F. Jiang, W. L. Gao,*, R. H. Cong, T. Yang,* Structure-induced Lewis-base Ga4B2O9 and its superior performance in Knoevenagel condensation reaction，Mol. Catal. 490 (2020) 110914
4) W. L. Wang, C. M. Zeng, Y. Yang, P. F. Jiang, W. L.Gao,* R. H. Cong, T. Yang,* Continuous solid solutions constructed from two isostructural octahedron-based molecular sieves: preparation, acidity regulation and catalytic application in Strecker reactions，New J. Chem., 2019, 43, 18184
5) H. W. Chen, W. L.Wang, Y.Yang, P. F. Jiang, W. L. Gao,* R. H. Cong, T. Yang，Solvent effect on the formation of active free radicals from H2O2 catalyzed by Cr-substituted PKU-1 aluminoborate: Spectroscopic investigation and reaction mechanism，Applied Catal. A, 588 (2019) 117283
6) S. X. Hu, W. L. Wang, M. F. Yue, G. J. Wang, W. L. Gao,* R. H. Cong, T. Yang*，Strong Lewis Base Ga4B2O9: Ga−O Connectivity Enhanced Basicity and Its Applications in the Strecker Reaction and Catalytic Conversion of n‑Propanol，ACS Appl. Mater. Interfaces 2018, 10, 15895−15904
7) W. L. Wang, S. X. Hu, L. J. Li, W. L. Gao*, R. H. Cong, T. Yang*, Octahedral-based redox molecular sieve M-PKU-1: isomorphous metal-substitution, catalytic oxidation of sec-alcohol and related catalytic mechanism, J. Catal. 2017, 352, 130-141
8) W. L. Wang, S. Y. Zhang, S. X. Hu, D. Wang, W. L. Gao*, R. H. Cong, T. Yang*, Octahedron-based redox molecular sieves M-PKU-1 (M = Cr, Fe): A novel dual-centered solid acid catalyst for heterogeneously catalyzed Strecker reaction, Applied Catal. A: 542 (2017) 240-251
9) F. H. Zhang, W. L. Wang, S. X. Hu, X. T. Ma, W. L. Gao*, R. H. Cong, T. Yang*, “A nanosized aluminoborate (PKU-5) with Cr-centered octahedral framework: solid-phase synthesis, characterizations and catalytic ammoximation of cyclohexanone to cyclohexanone azine”, Applied Catal. A: 531 (2017) 60–68.
10) G. J. Wang, W. L. Wang, F. H. Zhang, W. L. Gao,* R. H. Cong, T. Yang,* “Octahedron-based gallium borates (Ga-PKU-1) with open-framework: acidity, catalytic dehydration and structure-activity relationship”, Catal. Sci. Technol., 2016, 6, 5992–6001.
11) W. L. Wang, Y. Wang, B. Wu, R. H. Cong, W. L. Gao,* B. Qin,* T. Yang, “Octahedra-based Molecular Sieve Alunimoborate (PKU-1) as Solid Acid for Heterogeneously Catalyzed Strecker Reaction” Catal. Commun. 2015, 58, 174-178.
12) J. Xiang, Q. Q. Li, G. J. Wang, J. Ju, R. H. Cong, W. Yin, W. L. Gao,* T. Yang,* “(Al1-xCrx)4B6O15 (0.08 ≤ x ≤ 0.14): Metal Borates Catalyze the Dehydration of Methanol into Dimethyl Ether” Mater. Res. Bull. 2015, 65, 279-286.
13) R. Wang, M. F. Yue, R. H. Cong, W. L. Gao,* T. Yang,* “Photocatalytic reduction of nitrate over chalcopyrite CuFe0.7Cr0.3S2 with high N2 selectivity”, J. Alloy Compd. 2015, 651, 731-736.
14) X. Huang, Y. Jing, J. Yang, J. Ju, R. H. Cong, W. L. Gao,* T. Yang,* “Flower-like Nanostructure MNb2O6 (M = Mn, Zn) with High Surface Area: Hydrothermal Synthesis and Enhanced Photocatalytic Performance” Mater. Res. Bull. 2014, 51, 271-276.
15) J. Yang, M. F. Yue, J. Ju, R. H. Cong, W. L. Gao,* T. Yang,* “Co-molten solvothermal method for synthesizing chalcopyrite CuFe1-xCrxS2 (x ≤ 0.4): high photocatalytic activity for nitrate ions reduction” Dalton Trans. 2014, 43, 15385-15390.
16) W. L. Gao, Y. Jing, J. Yang, Z. Y. Zhou, D. F. Yang, J. L. Sun, J. H. Lin, R. H. Cong,* T. Yang,* “Open-framework Gallium Borate with Boric and Metaboric Acid Molecules inside Structural Channels Showing Photocatalysis to Water Splitting” Inorg. Chem. 2014, 53, 2346-2366
17) D. F. Yang, Y. Jing, Y. Zhang, X. M. Liu, Z. S. Lin, R. H. Cong,* W. L. Gao,* T. Yang, “CdB10O14(OH)4•H2O with an unprecedented decaborate fundamental building block”, Mater. Res. Bull. 2013, 48, 270-276.
18) D. F. Yang, R. H. Cong, W. L. Gao,* T. Yang,* “Boric acid flux synthesis, structure and magnetic property of MB12O14(OH)10 (M = Mn, Fe, Zn)”, J. Solid State Chem. 2013, 201, 29-34.
19) W. L. Gao, Y. X. Wang, G. B. Li, F. H. Liao, L. P. You, J. H. Lin*, Synthesis and Structure of an Aluminum Borate Chloride Consisting of 12-Membered Borate Rings and Aluminate Clusters, Inorg. Chem. 2008, 47, 7080–7082
20) W. L. Gao, T. Yang, Y. X. Wang, G. B. Li, Fuhui Liao, J. H. Lin,* Synthesis, characterization and catalytic performance of Cr-incorporated Aluminoborate octahedral molecular sieves, J. Phys. Chem. B, 2005, 109, 22775-22779
21) W. L. Gao, R. C. Jin, J. X. Chen, H. S. Zeng, F. X. Zhang, N. J. Guan,* Titania-Supported Bimetallic Catalysts for Photocatalytic Reduction of Nitrate, Catal. Today, 2004, 90, 331-336
22) W. L. Gao, X. X. Guan, J. X. Chen, R. C. Jin, F. X. Zhang, N. J. Guan,* Catalytic reduction of nitrite ions in drinking water over Pd-Cu/TiO2 bimetallic catalyst, Cataly. Today, 2004, 93-95 C, 331-337
23) W. L. Gao, N. J. Guan,* J. X. Chen, H. S. Zeng, Z. G. Liu, Titania Supported Pd-Cu Bimetallic Catalyst for the Reduction of Nitrate in Drinking Water, Appl. Catal. B: Environ., 2003, 46, 341-351
24) W. L. Gao, R. C. Jin, J. X. Chen, F. X. Zhang, Z. G. Liu, N. J. Guan,* Titania Supported Pd-Cu Bimetallic Catalyst for the Reduction of Nitrite in Drinking Water, Catal. Lett., 2003, 91, 25-30
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